Performance of Fixed-Bed Adsorption Reactor for Total Chromium Removal from Batik Wastewater Using Bioadsorbents and Zeolite

Winda Nurmalia Rizqy (1), Raden Kokoh Haryo Putro (2), Praditya Sigit Ardisty Sitogasa Sitogasa (3)
(1) Environmental Engineering Department, Faculty of Science and Technology, Universitas Pembangunan Nasional Veteran Jawa Timur, Surabaya. Indonesia
(2) Environmental Engineering Department, Faculty of Science and Technology, Universitas Pembangunan Nasional Veteran Jawa Timur, Surabaya. Indonesia
(3) Environmental Engineering Department, Faculty of Science and Technology, Universitas Pembangunan Nasional Veteran Jawa Timur, Surabaya. Indonesia
How to cite (AJARCDE) :
Rizqy, W. N., Putro, R. K. H., & Sitogasa, P. S. A. S. (2026). Performance of Fixed-Bed Adsorption Reactor for Total Chromium Removal from Batik Wastewater Using Bioadsorbents and Zeolite. AJARCDE (Asian Journal of Applied Research for Community Development and Empowerment), 10(1), 190–194. https://doi.org/10.29165/ajarcde.v10i1.921

Industrial batik wastewater contains total chromium, a heavy metal that can pollute aquatic environments. This study aims to evaluate the performance of a fixed-bed adsorption reactor in reducing total chromium concentrations in batik wastewater using coconut shell, corn cob, and zeolite adsorbents. The batik wastewater was obtained from Jemursari, Surabaya, with an initial total chromium concentration of 2.349-2.374 mg/L and a pH of 8. The bioadsorbents were prepared through carbonization at 500–600 °C, followed by chemical activation using 3 M H?PO?. The adsorption process was conducted continuously in a 5 L laboratory-scale fixed-bed reactor, with sampling times at 10, 40, 70, and 100 minutes. The results showed that total chromium removal efficiency increased significantly within the first 40 minutes for all adsorbents. The highest removal efficiency was achieved using zeolite at 87.8%, followed by coconut shell at 81.9% and corn cob at 73.1%. The superior performance of zeolite was attributed to its ion-exchange mechanism and physical properties, which are well-suited to continuous-flow systems.


Contribution to Sustainable Development Goals (SDGs):
SDG 6: Clean Water and Sanitation
SDG 12: Responsible Consumption and Production
SDG 11: Sustainable Cities and Communities
SDG 14 : Life Below Water

[1] R. F. Diba, V. Amalia, E. P. Hadisantoso, and Y. Rohmatulloh, “Adsorpsi Ion Logam Tembaga(II) dalam Air Dengan Serbuk Tulang Ikan Gurame (Osphronemus gourami Lac),” al-Kimiya, vol. 4, no. 2, pp. 105–112, 2019, doi: 10.15575/ak.v4i2.5091.

[2] E. Ayuningtyas, “Penurunan Kadar Warna dan Fenol Air Limbah Batik menggunakan Metode Advanced Oxidation Processes (AOPs) Berbasis Ozon-GAC,” J. Rekayasa Lingkung., vol. 20, no. 2, pp. 31–37, 2020, [Online]. Available: http://journal.ity.ac.id/index.php/JRL/article/view/53%0Ahttp://journal.ity.ac.id/index.php/JRL/article/download/53/48.

[3] L. Dini, R. A. Kusumadewi, and R. Hadisoebroto, “ADSORPSI LOGAM BERAT KROM (Cr) DAN ZAT WARNA DENGAN ADSORBEN KULIT PISANG KEPOK DALAM AIR LIMBAH BATIK,” J. Reka Lingkung., vol. 11, no. 1, pp. 37–48, 2023, doi: 10.26760/rekalingkungan.v11i1.37-48.

[4] L. N. U. R. FADILLA, “Sebaran Pencemaran Logam Berat Kromium Heksavalen (Cr-Vi) Dan Chemical Oxidation Demand (Cod) Pada Badan Air Di Sekitar Tpa Piyungan, Bantul,” 2022.

[5] D. Majid, P. Studi, T. Lingkungan, U. Pgri, and A. Buana, “Penurunan Kadar Bod , Cod Dan Turbiditas Limbah Cair Industri Batik Melalui Metode Kombinasi Pretreatment Filtrasi Adsorpsi Dan Elektrokoagulasi,” vol. 11, no. 3, pp. 258–269, 2023.

[6] W. Astuti, A. Dwi Handayani, and D. A. Wulandari, “Adsorpsi Methyl Violet oleh Karbon Aktif dari Limbah Tempurung Kelapa dengan Aktivator ZnCl2 Menggunakan Pemanasan Gelombang Mikro,” J. Rekayasa Kim. Lingkung., vol. 13, no. 2, pp. 189–199, 2018, doi: 10.23955/rkl.v13i2.11945.

[7] A. Frenly Simanullang, “Karakterisasi Sifat Fisis Papan Partikel Limbah Tongkol Jagung dengan Resin Epoxy Isosianat,” J. Ilmu dan Inov. Fis., vol. 5, no. 1, pp. 82–87, 2021, doi: 10.24198/jiif.v5i1.30692.

[8] N. Grifasi, B. Ziantoni, D. Fino, and M. Piumetti, Fundamental properties and sustainable applications of the natural zeolite clinoptilolite, vol. 32, no. 48. Springer Berlin Heidelberg, 2025.

[9] S. Meftah, K. Meftah, N. Babassa, K. Malous, M. Drissi, and A. Amahrous, The versatility and effectiveness of bio ? adsorbents in the removal of chemical pollutants from water?: adsorption mechanisms , optimization by ANN and RSM , SWOT analysis , and contribution to the 3rd and 6 th Sustainable Development Goals. Springer International Publishing, 2025.

[10] N. Apriyani, “Industri Batik: Kandungan Limbah Cair dan Metode Pengolahannya,” Media Ilm. Tek. Lingkung., vol. 3, no. 1, pp. 21–29, 2018, doi: 10.33084/mitl.v3i1.640.

[11] N. E. Alam, A. S. Mia, F. Ahmad, and M. Rahman, “An overview of chromium removal techniques from tannery effluent,” Appl. Water Sci., vol. 10, no. 9, pp. 1–22, 2020, doi: 10.1007/s13201-020-01286-0.

[12] M. Akhtar, M. Sarfraz, M. Ahmad, and N. Raza, “Use of low-cost adsorbent for waste water treatment?: Recent progress , new trend and future perspectives,” Desalin. Water Treat., vol. 321, no. September 2024, p. 100914, 2025, doi: 10.1016/j.dwt.2024.100914.

[13] G. O. Ogbeh, A. O. Ogunlela, C. O. Akinbile, and R. T. Iwar, “Adsorption of organic micropollutants in water: A review of advances in modelling, mechanisms, adsorbents, and their characteristics,” Environ. Eng. Res., vol. 30, no. 2, pp. 230730–230733, Apr. 2025, doi: 10.4491/eer.2023.733.

[14] H. I. Sholikhah and H. R. Putri, “Pengaruh Konsentrasi Aktivator Asam Fosfat ( H 3 PO 4 ) pada Pembuatan Karbon Aktif dari Sabut Kelapa terhadap Adsorpsi Logam Kromium,” vol. 5, no. 1, pp. 3–8.

[15] H. Patel, “Fixed-bed column adsorption study: a comprehensive review,” Appl. Water Sci., vol. 9, no. 3, pp. 1–17, 2019, doi: 10.1007/s13201-019-0927-7.

[16] W. Ananas and H. P. O. Activator, “Uji karakteristik fisik pembuatan karbon aktif dari limbah daun nanas (,” vol. 12, no. 02, pp. 4–11, 2021.

[17] A. Nurrahman, E. Permana, D. R. Gusti, and I. Lestari, “Pengaruh Konsentrasi Aktivator Terhadap Kualitas Karbon Aktif dari Batubara Lignit,” vol. 4, no. 2, pp. 44–53, 2021, doi: 10.33087/daurling.v4i2.86.

[18] R. Cocco and J. Wei, “50 years of Geldart classification,” Powder Technol., vol. 428, no. July, p. 118861, 2023, doi: 10.1016/j.powtec.2023.118861.

[19] S. A. Roshan and A. Mofidi, “Comparison of Fixed and Fluidized Beds Adsorber with Economic , Engineering , and Environmental approach,” pp. 165–174, 2014.

[20] E. H. Sujiono, D. Zabrian, V. Zharvan, and N. A. Humairah, “Results in Chemistry Fabrication and characterization of coconut shell activated carbon using variation chemical activation for wastewater treatment application,” Results Chem., vol. 4, no. January, p. 100291, 2022, doi: 10.1016/j.rechem.2022.100291.

[21] E. Adsorpsi, K. Aktif, and A. T. Batubara, “Jurnal Inovasi Global KELAPA TERHADAP KANDUNGAN BESI ( Fe ) DAN ASAM TAMBANG BATUBARA,” vol. 2, no. 2, pp. 1–14, 2024, doi: 10.58344/jig.v2i2.55.

[22] S. Tang, Y. Chen, R. Xie, W. Jiang, and Y. Jiang, “Preparation of activated carbon from corn cob and its adsorption behavior on Cr(VI) removal.,” Water Sci. Technol. a J. Int. Assoc. Water Pollut. Res., vol. 73, no. 11, pp. 2654–2661, 2016, doi: 10.2166/wst.2016.120.

[23] P. Syaifie, A. Taufiq, and G. Wardhani, “SINTESIS, KARAKTERISASI DAN APLIKASI ZEOLIT BERBAHAN DASAR KAOLIN DAN ABU SEKAM PADI UNTUK ADSORPSI LOGAM TEMBAGA DAN KROM DALAM LIMBAH CAIR INDUSTRI PELAPISAN LOGAM,” J. Teknol. Bahan dan Barang Tek., vol. 9, p. 17, Jun. 2019, doi: 10.37209/jtbbt.v9i1.129.

[24] E. Pérez-Botella, S. Valencia, and F. Rey, “Zeolites in Adsorption Processes: State of the Art and Future Prospects,” Chem. Rev., vol. 122, no. 24, pp. 17647–17695, Dec. 2022, doi: 10.1021/acs.chemrev.2c00140.

Downloads

Download data is not yet available.