Physical and Mechanical Properties: Effect of Substitution of EFB Filler on the Processing of Lump-Based Motorcycle Foot Pad Compounds

Supriyanto Supriyanto (1), Giffary Pramafisi Soeherman (2), Pridata Gina Putri (3)
(1) Department of Plantation Crop Cultivation, Lampung State Polytechnic, Lampung 35141, Indonesia
(2) Department of Agroindustry Technology, Lampung State Polytechnic, Lampung 35141, Indonesia
(3) Department of Agroindustry Technology, Lampung State Polytechnic, Lampung 35141, Indonesia
Fulltext View | Download
How to cite (AJARCDE) :
Supriyanto, S., Soeherman, G. P., & Pridata Gina Putri. (2026). Physical and Mechanical Properties: Effect of Substitution of EFB Filler on the Processing of Lump-Based Motorcycle Foot Pad Compounds. AJARCDE (Asian Journal of Applied Research for Community Development and Empowerment), 10(3), 209–220. https://doi.org/10.29165/ajarcde.v10i3.1000

Lump is one of the processed rubber materials derived from latex of rubber trees and clusters of latex obtained from the Hevea Brasiliensis tree. Generally, lumps can be utilized as the basic material for component manufacturing. In the production of component products, additives such as filling materials, vulcanization agents, plasticizers, activators, antioxidants, and accelerators are required. This research utilizes EFB charcoal as a filling material in the production of rubber components to substitute carbon black, which will be used as a motorcycle footrest pad. The objective of this study is to analyze the characteristics of rubber components for motorcycle footrest pads with EFB filler as a filling material, and to obtain the best formulation in rubber component manufacturing that meets the hardness test parameters according to the Indonesian National Standard (SNI). The method used is a Completely Randomized Design (CRD) with one factor, namely the rubber component formula. This study consists of 5 treatments repeated 4 times, resulting in 20 experimental units. The results of the study showed that the physical and mechanical properties of each substitution treatment had the same characteristics with a reduction or decrease in test results for each test parameter carried out. However, based on the test results for each test parameter carried out, there were only 4 treatments that were still included in the SNI standard for hardness tests for step motors, namely F1 (0:60), F2(10:50), F3(20:40) and F4(30:30).. While the F5(40:20)treatment was still below the SNI standard. The best treatment was still obtained in the F2(10:50) treatment with a hardness value of 69.05 Shore A.


Contribution to Sustainable Development Goals (SDGs):
SDGs 8: Decent Work and Economic Growth
SDGs 9: Industry, Innovation and Infrastructure
SDGs 12: Responsible Consumption and Production
SDGs 13: Climate Action
SDGs 15: Life on Land

[1] M. Mustangin, “AGRO FABRICA Jurnal Teknik Pengolahan Hasil Perkebunan Kelapa Sawit dan Karet Available online,” Agro Fabr., vol. 1, no. 2, pp. 7–15, 2021.

[2] G. R. Putri, K. Nadiyah, N. Rishelin, and R. Futeri, “Pengendalian Kualitas Mooney Viscosity ( MV ) dan Plasticity Retention Index ( PRI ) dalam Crumb rubber SIR 3CV 60 dengan Metode Statistical Quality Control ( SQC ) di Perusahaan Karet,” vol. XVIII, no. 3, pp. 315–328, 2024.

[3] B. Prastia, Bursamin, R. Fernandes, and S. Hidayad, “Analysis Of Dryer Control System For Non-Conformity Of The Crumb Rubber Products In PT. Bukit Angkasa Makmur Bengkulu,” J. Sains Agro, vol. 10, no. 2, pp. 211–218, 2025.

[4] M. Rosyidah, “World Development Sustainability Optimization of environmentally friendly coagulants based on circular economy and SDGs in the rubber latex industry in Indonesia,” World Dev. Sustain., vol. 8, no. December 2025, p. 100274, 2026, doi: 10.1016/j.wds.2026.100274.

[5] A. Sani et al., “Cup lump rubber and natural rubber latex biopolymers as promising modifiers for asphalt binders and mixtures?: A review,” J. Road Eng., vol. 5, no. 4, pp. 531–553, 2025, doi: 10.1016/j.jreng.2025.06.003.

[6] D. S. Agustina, R. Nurmalina, and A. Fariyanti, “Research on World Agricultural Economy An Empirical Study on Indonesia ’ s Participation in the Global,” vol. 06, no. 04, pp. 497–512, 2025.

[7] M. Andriyanto and M. H. Fendiyanto, “Penggunaan Senyawa osmolit dan Alkalin Pada Penyadapan Tanmaman Karet (Hevea brasiliensis),” J. Agro Estate, vol. 3, no. 2, pp. 110–120, 2019, doi: 10.47199/jae.v3i2.101.

[8] R. B. Pereira Negri, A. H. Monteiro Fonseca Thomé da Silva, A. M. Furtado de Sousa, A. L. N. da Silva, and E. Brum Dutra da Rocha, “Improved mechanical and rheological behavior of nitrile rubber reinforced with multi-walled carbon nanotubes and carbon black dual-filler system,” Mater. Today Commun., vol. 26, no. November, 2021, doi: 10.1016/j.mtcomm.2020.101884.

[9] Sunali, J. Mago, A. Negi, K. K. Pant, and S. Fatima, “Development of natural rubber-bamboo biochar composites for vibration and noise control applications,” J. Clean. Prod., vol. 373, p. 133760, 2022, doi: https://doi.org/10.1016/j.jclepro.2022.133760.

[10] S. Supriyanto, “PengaruhPenggunaanSubstrat pada Pengomposan Secara Anaerob Menggunakan Tandan Kosong Kelapa Sawit (TKKS) dari Limbah Media Jamur Merang,” Daun J. Ilm. Pertan. dan Kehutan., vol. 7, no. 1, pp. 50–66, 2020, doi: 10.33084/daun.v7i1.1606.

[11] P. Herianti and D. A. Permata, “Optimization of Oil Palm Empty Fruit Bunches Cellulose-based Bioplastic Formulation with Response Surface Methodology ( RSM ),” vol. 9, no. 1, 2025.

[12] I. Surya, L. Sukeksi, and N. Hayeemasae, “Studies on cure index, swelling behaviour, tensile and thermooxidative properties of natural rubber compounds in the presence of alkanolamide,” IOP Conf. Ser. Mater. Sci. Eng., vol. 309, no. 1, 2018, doi: 10.1088/1757-899X/309/1/012060.

[13] N. I. D. Arista, C. E. Natalia, I. L. Sinaga, and ..., “The potential of circular economy in the oil palm plantation to industry,” J. …, 2024, [Online]. Available: https://journal-iasssf.com/index.php/JSSEW/article/view/311

[14] G. P. Soeherman et al., “Upcycling Cangkang Kelapa Sawit Menjadi Green Filler Teraktivasi Ultrasonik dan Aplikasinya Sebagai Pengisi Kompon Karet,” vol. 19, no. 1, pp. 25–32, 2025, doi: 10.24198/jt.vol19n1.4.

[15] D. Y. S. Low et al., “Self-healing synthetic rubber composites: review of recent progress and future directions towards sustainability,” Mater. Today Sustain., vol. 24, 2023, doi: 10.1016/j.mtsust.2023.100545.

[16] D. Prasetyo Bangun and S. Wulung R B, “Optimizing The Use of Carbon Black in Dock Bearings By Considering The Physical Properties of The Product Optimisasi Penggunaan Carbon Black Pada Bantalan Dermaga dengan Mempertimbangkan Sifat Fisis Produk,” Progr. Stud. Teknol. Pengolah. Karet dan Plast. Politek. Yogyakarta, vol. 8, no. 1, pp. 14–23, 2023.

[17] E. B. D. da Rocha et al., “Cyclic uniaxial stress-strain test and rheological behavior of carbon black/metakaolin dual-filler system used in nitrile rubber compounds,” Polym. Test., vol. 77, no. February, p. 105906, 2019, doi: 10.1016/j.polymertesting.2019.105906.

[18] M. F. Omar et al., “A Comprehensive Review of Natural Rubber Composites?: Properties , Compounding Aspects , and Renewable Practices with Natural Fibre Reinforcement,” 2024, doi: 10.32604/jrm.2024.057248.

[19] G. Pudhupalayam Muthukutti et al., “Sustainable polymer composites from agro and municipal green wastes: a comprehensive review of materials, properties, and applications,” J. Mater. Cycles Waste Manag., vol. 27, no. 5, pp. 3121–3142, 2025, doi: 10.1007/s10163-025-02319-z.

[20] B. Mensah, K. C. Gupta, G. Kang, H. Lee, and C. Nah, “A comparative study on vulcanization behavior of acrylonitrile-butadiene rubber reinforced with graphene oxide and reduced graphene oxide as fillers,” Polym. Test., vol. 76, pp. 127–137, 2019, doi: https://doi.org/10.1016/j.polymertesting.2019.01.026.

[21] A. D. Aguilar et al., “Characterization dataset of oil palm empty fruit bunch (OPEFB) fibers – Natural reinforcement/filler for materials development,” Data Br., vol. 45, 2022, doi: 10.1016/j.dib.2022.108618.

[22] Supriyanto, D. Riniarti, and W. R. Hartari, “PENINGKATAN KARAKTERISTIK SIFAT FISIKA SERAT PEMBUATAN BIODEGRADABLE POT,” vol. 4, no. 1, 2025.

[23] T. Mishra, P. Mandal, A. K. Rout, and D. Sahoo, “A state-of-the-art review on potential applications of natural fiber-reinforced polymer composite filled with inorganic nanoparticle,” Compos. Part C Open Access, vol. 9, no. July, p. 100298, 2022, doi: 10.1016/j.jcomc.2022.100298.

[24] D. Syafei and W. Prendika, “Pembuatan dan Karakterisasi Komposit Termoplastik Elastomer dari Karet Alam-Polipropilena Bekas dengan Filler Tandan Kosong Kelapa Sawit,” J. Indones. Soc. Intergrated Chem., vol. 13, no. 1, pp. 52–57, 2021.

[25] T. Ohashi, A. Tohsan, and Y. Ikeda, “Role of in situ generated silica for rubber science and technology,” Polym. Int., vol. 66, no. 2, pp. 250–259, Feb. 2017, doi: https://doi.org/10.1002/pi.5155.

[26] M. F. Omar et al., “A Comprehensive Review of Natural Rubber Composites: Properties, Compounding Aspects, and Renewable Practices with Natural Fibre Reinforcement,” J. Renew. Mater., vol. 13, no. 3, pp. 497–538, 2025, doi: https://doi.org/10.32604/jrm.2024.057248.

[27] O. Kratina, M. Pöschl, and R. Sto?ek, “The effect of apparent density of sulfidic crosslink and their chemical nature on self-heat build-up in carbon black filled Natural Rubber under cyclic mechanical loading,” Polym. Degrad. Stab., vol. 227, p. 110871, 2024, doi: https://doi.org/10.1016/j.polymdegradstab.2024.110871.

[28] W. Kitisavetjit, Y. Nakaramontri, S. Pichaiyut, S. Wisunthorn, C. Nakason, and S. Kiatkamjornwong, “Influences of carbon nanotubes and graphite hybrid filler on properties of natural rubber nanocomposites,” Polym. Test., vol. 93, p. 106981, 2021, doi: 10.1016/j.polymertesting.2020.106981.

[29] A. A. Koriem, M. E. Abd El-Aziz, S. R. Salem, A. I. Hussain, and G. Turky, “Management of agricultural waste to manufacture biochar: An alternative reinforcing filler for carbon black in nitrile butadiene rubber composites,” J. Clean. Prod., vol. 428, p. 139360, 2023, doi: https://doi.org/10.1016/j.jclepro.2023.139360.

[30] A. Ahmad et al., “Development and characterisation of eco-friendly hybrid polymer composites from palm oil empty fruit bunch ( EFB ) fibre and glass fiber reinforced polyester for biomedical applications,” Mater. Technol., vol. 40, no. 1, 2025, doi: 10.1080/10667857.2025.2512017.

[31] W. Ribeiro and R. Brandalise, “Influence of pyrolysis temperature on biochar properties: Applications as a reinforcing filler in sbr and epdm elastomeric compounds,” J. Elastomers Plast., vol. 56, Oct. 2024, doi: 10.1177/00952443241289831.

[32] A. Tomczyk, “Biochar physicochemical properties?: pyrolysis temperature and feedstock kind effects,” Rev. Environ. Sci. Bio/Technology, vol. 19, no. 1, pp. 191–215, 2020, doi: 10.1007/s11157-020-09523-3.

[33] M. Dadkhah and M. Messori, “Materials Today Sustainability A comprehensive overview of conventional and bio-based fillers for rubber formulations sustainability,” Mater. Today Sustain., vol. 27, no. June, p. 100886, 2024, doi: 10.1016/j.mtsust.2024.100886.

[34] L. Karunanayake, T. Etampawala, D. J. De Silva, and J. Bandara, “Role and potential of biochar as a sustainable alternative reinforcing filler to carbon black in rubber composites,” Biochar, 2025, doi: 10.1007/s42773-025-00429-3.

[35] S. Hait et al., “Unlocking the potential of lignin: Towards a sustainable solution for tire rubber compound reinforcement,” J. Clean. Prod., vol. 470, p. 143274, 2024, doi: https://doi.org/10.1016/j.jclepro.2024.143274.

[36] H. Shi, M. Wang, and C. Wan, “Progress in Polymer Science Detecting polymer network architecture and dynamics through the phase angle in oscillatory shear rheology,” Prog. Polym. Sci., vol. 173, p. 102068, 2026, doi: 10.1016/j.progpolymsci.2025.102068.

[37] J. Cui, D. Wei, and F. Zeng, “Effects of Aggregation Degree and Cross-Linking Density on the Viscoelasticity of CNTs/CB-Filled Natural Rubber Composites: A Coarse-Grained Molecular Dynamics Simulation,” Polym. Compos., vol. 47, no. 5, pp. 3959–3970, Mar. 2026, doi: https://doi.org/10.1002/pc.70400.

[38] M. E. Abd El-Aziz, E. S. Shafik, M. L. Tawfic, and S. M. M. Morsi, “Biochar from waste agriculture as reinforcement filer for styrene/butadiene rubber,” Polym. Compos., vol. 43, no. 3, pp. 1295–1304, Mar. 2022, doi: https://doi.org/10.1002/pc.26448.

[39] Z.-L. Wan et al., “Data-Driven Exploration of Polymer Processing Effects on the Mechanical Properties in Carbon Black-Reinforced Rubber Composites,” Chinese J. Polym. Sci., vol. 42, no. 12, pp. 2038–2047, 2024, doi: 10.1007/s10118-024-3216-3.

[40] S. Nie, J. Lacayo-Pineda, N. Willenbacher, and M. Wilhelm, “Aging of natural rubber studied via Fourier-transform rheology and double quantum NMR to correlate local chain dynamics with macroscopic mechanical response,” Polymer (Guildf)., vol. 181, no. September, p. 121804, 2019, doi: 10.1016/j.polymer.2019.121804.

[41] E. M. Ginting, N. Bukit, E. Frida, and B. F. Bukit, “Microstructure and thermal properties of natural rubber compound with palm oil boilers ash for nanoparticle filler,” Case Stud. Therm. Eng., vol. 17, Feb. 2020, doi: 10.1016/j.csite.2019.100575.

[42] G. Butuc, K. van Leerdam, B. Rossenaar, A. Talma, and A. Blume, “Deciphering the crosslink mechanism of dual cure EP(D)M and CTS rubber compounds for reduced oil swell,” Polym. Test., vol. 145, p. 108736, 2025, doi: https://doi.org/10.1016/j.polymertesting.2025.108736.

[43] K. Y. Sianturi, A. F. Nugraha, K. Y. Sianturi, A. F. Nugraha, B. Kristaura, and M. Chalid, “Enhancing Compatibility and Mechanical Properties of Natural Rubber Composites Enhancing Compatibility and Mechanical Properties of Oil Palm Empty Fruit Bunch ( OPEFB ) Fiber-Reinforced Natural Rubber Composites with Latex-Starch Hybrid Coupling Agent,” vol. 2, no. 1, 2023, doi: 10.7454/jmef.v2i1.1029.

[44] S. Zahmatkesh and R. Rizvi, “Evaluating surface texturing technologies of rubber composites on ice using a novel high-velocity tribotest method,” Tribol. Int., vol. 206, Jun. 2025, doi: 10.1016/j.triboint.2025.110538.

[45] J. J. Dale et al., “Exploring inverse vulcanisation mechanisms from the perspective of dark sulfur,” Eur. Polym. J., vol. 195, Aug. 2023, doi: 10.1016/j.eurpolymj.2023.112198.

[46] H. E. Mayasari, “The blending of EPDM/NR with maleic anhydride as compatibilizer: Comparing the effect of accelerators on cure characteristic and mechanical properties,” Indones. J. Chem., vol. 19, no. 1, pp. 106–114, 2019, doi: 10.22146/ijc.27730.

[47] C. Dwivedi, S. Manjare, and S. K. Rajan, “Recycling of waste tire by pyrolysis to recover carbon black: Alternative & environment-friendly reinforcing filler for natural rubber compounds,” Compos. Part B Eng., vol. 200, no. April, p. 108346, 2020, doi: 10.1016/j.compositesb.2020.108346.

[48] H. Harahap, H. Nasution, R. Manurung, A. Yustira, and A. A. Rashid, “Physical characteristics of biodegradable pots from empty fruit bunches (EFB) and sawdust waste as planting media,” Case Stud. Chem. Environ. Eng., vol. 11, Jun. 2025, doi: 10.1016/j.cscee.2025.101193.

[49] C. Ramos-oliveira, M. Ferreira, I. Belo, and A. Oliva-teles, “Effectiveness of High-Solid Loading Treatments to Enhance Nutrient and Antioxidant Bioavailability in Codium tomentosum,” pp. 1–16, 2025.

[1] M. Mustangin, “AGRO FABRICA Jurnal Teknik Pengolahan Hasil Perkebunan Kelapa Sawit dan Karet Available online,” Agro Fabr., vol. 1, no. 2, pp. 7–15, 2021.

[2] G. R. Putri, K. Nadiyah, N. Rishelin, and R. Futeri, “Pengendalian Kualitas Mooney Viscosity ( MV ) dan Plasticity Retention Index ( PRI ) dalam Crumb rubber SIR 3CV 60 dengan Metode Statistical Quality Control ( SQC ) di Perusahaan Karet,” vol. XVIII, no. 3, pp. 315–328, 2024.

[3] B. Prastia, Bursamin, R. Fernandes, and S. Hidayad, “Analysis Of Dryer Control System For Non-Conformity Of The Crumb Rubber Products In PT. Bukit Angkasa Makmur Bengkulu,” J. Sains Agro, vol. 10, no. 2, pp. 211–218, 2025.

[4] M. Rosyidah, “World Development Sustainability Optimization of environmentally friendly coagulants based on circular economy and SDGs in the rubber latex industry in Indonesia,” World Dev. Sustain., vol. 8, no. December 2025, p. 100274, 2026, doi: 10.1016/j.wds.2026.100274.

[5] A. Sani et al., “Cup lump rubber and natural rubber latex biopolymers as promising modifiers for asphalt binders and mixtures?: A review,” J. Road Eng., vol. 5, no. 4, pp. 531–553, 2025, doi: 10.1016/j.jreng.2025.06.003.

[6] D. S. Agustina, R. Nurmalina, and A. Fariyanti, “Research on World Agricultural Economy An Empirical Study on Indonesia ’ s Participation in the Global,” vol. 06, no. 04, pp. 497–512, 2025.

[7] M. Andriyanto and M. H. Fendiyanto, “Penggunaan Senyawa osmolit dan Alkalin Pada Penyadapan Tanmaman Karet (Hevea brasiliensis),” J. Agro Estate, vol. 3, no. 2, pp. 110–120, 2019, doi: 10.47199/jae.v3i2.101.

[8] R. B. Pereira Negri, A. H. Monteiro Fonseca Thomé da Silva, A. M. Furtado de Sousa, A. L. N. da Silva, and E. Brum Dutra da Rocha, “Improved mechanical and rheological behavior of nitrile rubber reinforced with multi-walled carbon nanotubes and carbon black dual-filler system,” Mater. Today Commun., vol. 26, no. November, 2021, doi: 10.1016/j.mtcomm.2020.101884.

[9] Sunali, J. Mago, A. Negi, K. K. Pant, and S. Fatima, “Development of natural rubber-bamboo biochar composites for vibration and noise control applications,” J. Clean. Prod., vol. 373, p. 133760, 2022, doi: https://doi.org/10.1016/j.jclepro.2022.133760.

[10] S. Supriyanto, “PengaruhPenggunaanSubstrat pada Pengomposan Secara Anaerob Menggunakan Tandan Kosong Kelapa Sawit (TKKS) dari Limbah Media Jamur Merang,” Daun J. Ilm. Pertan. dan Kehutan., vol. 7, no. 1, pp. 50–66, 2020, doi: 10.33084/daun.v7i1.1606.

[11] P. Herianti and D. A. Permata, “Optimization of Oil Palm Empty Fruit Bunches Cellulose-based Bioplastic Formulation with Response Surface Methodology ( RSM ),” vol. 9, no. 1, 2025.

[12] I. Surya, L. Sukeksi, and N. Hayeemasae, “Studies on cure index, swelling behaviour, tensile and thermooxidative properties of natural rubber compounds in the presence of alkanolamide,” IOP Conf. Ser. Mater. Sci. Eng., vol. 309, no. 1, 2018, doi: 10.1088/1757-899X/309/1/012060.

[13] N. I. D. Arista, C. E. Natalia, I. L. Sinaga, and ..., “The potential of circular economy in the oil palm plantation to industry,” J. …, 2024, [Online]. Available: https://journal-iasssf.com/index.php/JSSEW/article/view/311

[14] G. P. Soeherman et al., “Upcycling Cangkang Kelapa Sawit Menjadi Green Filler Teraktivasi Ultrasonik dan Aplikasinya Sebagai Pengisi Kompon Karet,” vol. 19, no. 1, pp. 25–32, 2025, doi: 10.24198/jt.vol19n1.4.

[15] D. Y. S. Low et al., “Self-healing synthetic rubber composites: review of recent progress and future directions towards sustainability,” Mater. Today Sustain., vol. 24, 2023, doi: 10.1016/j.mtsust.2023.100545.

[16] D. Prasetyo Bangun and S. Wulung R B, “Optimizing The Use of Carbon Black in Dock Bearings By Considering The Physical Properties of The Product Optimisasi Penggunaan Carbon Black Pada Bantalan Dermaga dengan Mempertimbangkan Sifat Fisis Produk,” Progr. Stud. Teknol. Pengolah. Karet dan Plast. Politek. Yogyakarta, vol. 8, no. 1, pp. 14–23, 2023.

[17] E. B. D. da Rocha et al., “Cyclic uniaxial stress-strain test and rheological behavior of carbon black/metakaolin dual-filler system used in nitrile rubber compounds,” Polym. Test., vol. 77, no. February, p. 105906, 2019, doi: 10.1016/j.polymertesting.2019.105906.

[18] M. F. Omar et al., “A Comprehensive Review of Natural Rubber Composites?: Properties , Compounding Aspects , and Renewable Practices with Natural Fibre Reinforcement,” 2024, doi: 10.32604/jrm.2024.057248.

[19] G. Pudhupalayam Muthukutti et al., “Sustainable polymer composites from agro and municipal green wastes: a comprehensive review of materials, properties, and applications,” J. Mater. Cycles Waste Manag., vol. 27, no. 5, pp. 3121–3142, 2025, doi: 10.1007/s10163-025-02319-z.

[20] B. Mensah, K. C. Gupta, G. Kang, H. Lee, and C. Nah, “A comparative study on vulcanization behavior of acrylonitrile-butadiene rubber reinforced with graphene oxide and reduced graphene oxide as fillers,” Polym. Test., vol. 76, pp. 127–137, 2019, doi: https://doi.org/10.1016/j.polymertesting.2019.01.026.

[21] A. D. Aguilar et al., “Characterization dataset of oil palm empty fruit bunch (OPEFB) fibers – Natural reinforcement/filler for materials development,” Data Br., vol. 45, 2022, doi: 10.1016/j.dib.2022.108618.

[22] Supriyanto, D. Riniarti, and W. R. Hartari, “PENINGKATAN KARAKTERISTIK SIFAT FISIKA SERAT PEMBUATAN BIODEGRADABLE POT,” vol. 4, no. 1, 2025.

[23] T. Mishra, P. Mandal, A. K. Rout, and D. Sahoo, “A state-of-the-art review on potential applications of natural fiber-reinforced polymer composite filled with inorganic nanoparticle,” Compos. Part C Open Access, vol. 9, no. July, p. 100298, 2022, doi: 10.1016/j.jcomc.2022.100298.

[24] D. Syafei and W. Prendika, “Pembuatan dan Karakterisasi Komposit Termoplastik Elastomer dari Karet Alam-Polipropilena Bekas dengan Filler Tandan Kosong Kelapa Sawit,” J. Indones. Soc. Intergrated Chem., vol. 13, no. 1, pp. 52–57, 2021.

[25] T. Ohashi, A. Tohsan, and Y. Ikeda, “Role of in situ generated silica for rubber science and technology,” Polym. Int., vol. 66, no. 2, pp. 250–259, Feb. 2017, doi: https://doi.org/10.1002/pi.5155.

[26] M. F. Omar et al., “A Comprehensive Review of Natural Rubber Composites: Properties, Compounding Aspects, and Renewable Practices with Natural Fibre Reinforcement,” J. Renew. Mater., vol. 13, no. 3, pp. 497–538, 2025, doi: https://doi.org/10.32604/jrm.2024.057248.

[27] O. Kratina, M. Pöschl, and R. Sto?ek, “The effect of apparent density of sulfidic crosslink and their chemical nature on self-heat build-up in carbon black filled Natural Rubber under cyclic mechanical loading,” Polym. Degrad. Stab., vol. 227, p. 110871, 2024, doi: https://doi.org/10.1016/j.polymdegradstab.2024.110871.

[28] W. Kitisavetjit, Y. Nakaramontri, S. Pichaiyut, S. Wisunthorn, C. Nakason, and S. Kiatkamjornwong, “Influences of carbon nanotubes and graphite hybrid filler on properties of natural rubber nanocomposites,” Polym. Test., vol. 93, p. 106981, 2021, doi: 10.1016/j.polymertesting.2020.106981.

[29] A. A. Koriem, M. E. Abd El-Aziz, S. R. Salem, A. I. Hussain, and G. Turky, “Management of agricultural waste to manufacture biochar: An alternative reinforcing filler for carbon black in nitrile butadiene rubber composites,” J. Clean. Prod., vol. 428, p. 139360, 2023, doi: https://doi.org/10.1016/j.jclepro.2023.139360.

[30] A. Ahmad et al., “Development and characterisation of eco-friendly hybrid polymer composites from palm oil empty fruit bunch ( EFB ) fibre and glass fiber reinforced polyester for biomedical applications,” Mater. Technol., vol. 40, no. 1, 2025, doi: 10.1080/10667857.2025.2512017.

[31] W. Ribeiro and R. Brandalise, “Influence of pyrolysis temperature on biochar properties: Applications as a reinforcing filler in sbr and epdm elastomeric compounds,” J. Elastomers Plast., vol. 56, Oct. 2024, doi: 10.1177/00952443241289831.

[32] A. Tomczyk, “Biochar physicochemical properties?: pyrolysis temperature and feedstock kind effects,” Rev. Environ. Sci. Bio/Technology, vol. 19, no. 1, pp. 191–215, 2020, doi: 10.1007/s11157-020-09523-3.

[33] M. Dadkhah and M. Messori, “Materials Today Sustainability A comprehensive overview of conventional and bio-based fillers for rubber formulations sustainability,” Mater. Today Sustain., vol. 27, no. June, p. 100886, 2024, doi: 10.1016/j.mtsust.2024.100886.

[34] L. Karunanayake, T. Etampawala, D. J. De Silva, and J. Bandara, “Role and potential of biochar as a sustainable alternative reinforcing filler to carbon black in rubber composites,” Biochar, 2025, doi: 10.1007/s42773-025-00429-3.

[35] S. Hait et al., “Unlocking the potential of lignin: Towards a sustainable solution for tire rubber compound reinforcement,” J. Clean. Prod., vol. 470, p. 143274, 2024, doi: https://doi.org/10.1016/j.jclepro.2024.143274.

[36] H. Shi, M. Wang, and C. Wan, “Progress in Polymer Science Detecting polymer network architecture and dynamics through the phase angle in oscillatory shear rheology,” Prog. Polym. Sci., vol. 173, p. 102068, 2026, doi: 10.1016/j.progpolymsci.2025.102068.

[37] J. Cui, D. Wei, and F. Zeng, “Effects of Aggregation Degree and Cross-Linking Density on the Viscoelasticity of CNTs/CB-Filled Natural Rubber Composites: A Coarse-Grained Molecular Dynamics Simulation,” Polym. Compos., vol. 47, no. 5, pp. 3959–3970, Mar. 2026, doi: https://doi.org/10.1002/pc.70400.

[38] M. E. Abd El-Aziz, E. S. Shafik, M. L. Tawfic, and S. M. M. Morsi, “Biochar from waste agriculture as reinforcement filer for styrene/butadiene rubber,” Polym. Compos., vol. 43, no. 3, pp. 1295–1304, Mar. 2022, doi: https://doi.org/10.1002/pc.26448.

[39] Z.-L. Wan et al., “Data-Driven Exploration of Polymer Processing Effects on the Mechanical Properties in Carbon Black-Reinforced Rubber Composites,” Chinese J. Polym. Sci., vol. 42, no. 12, pp. 2038–2047, 2024, doi: 10.1007/s10118-024-3216-3.

[40] S. Nie, J. Lacayo-Pineda, N. Willenbacher, and M. Wilhelm, “Aging of natural rubber studied via Fourier-transform rheology and double quantum NMR to correlate local chain dynamics with macroscopic mechanical response,” Polymer (Guildf)., vol. 181, no. September, p. 121804, 2019, doi: 10.1016/j.polymer.2019.121804.

[41] E. M. Ginting, N. Bukit, E. Frida, and B. F. Bukit, “Microstructure and thermal properties of natural rubber compound with palm oil boilers ash for nanoparticle filler,” Case Stud. Therm. Eng., vol. 17, Feb. 2020, doi: 10.1016/j.csite.2019.100575.

[42] G. Butuc, K. van Leerdam, B. Rossenaar, A. Talma, and A. Blume, “Deciphering the crosslink mechanism of dual cure EP(D)M and CTS rubber compounds for reduced oil swell,” Polym. Test., vol. 145, p. 108736, 2025, doi: https://doi.org/10.1016/j.polymertesting.2025.108736.

[43] K. Y. Sianturi, A. F. Nugraha, K. Y. Sianturi, A. F. Nugraha, B. Kristaura, and M. Chalid, “Enhancing Compatibility and Mechanical Properties of Natural Rubber Composites Enhancing Compatibility and Mechanical Properties of Oil Palm Empty Fruit Bunch ( OPEFB ) Fiber-Reinforced Natural Rubber Composites with Latex-Starch Hybrid Coupling Agent,” vol. 2, no. 1, 2023, doi: 10.7454/jmef.v2i1.1029.

[44] S. Zahmatkesh and R. Rizvi, “Evaluating surface texturing technologies of rubber composites on ice using a novel high-velocity tribotest method,” Tribol. Int., vol. 206, Jun. 2025, doi: 10.1016/j.triboint.2025.110538.

[45] J. J. Dale et al., “Exploring inverse vulcanisation mechanisms from the perspective of dark sulfur,” Eur. Polym. J., vol. 195, Aug. 2023, doi: 10.1016/j.eurpolymj.2023.112198.

[46] H. E. Mayasari, “The blending of EPDM/NR with maleic anhydride as compatibilizer: Comparing the effect of accelerators on cure characteristic and mechanical properties,” Indones. J. Chem., vol. 19, no. 1, pp. 106–114, 2019, doi: 10.22146/ijc.27730.

[47] C. Dwivedi, S. Manjare, and S. K. Rajan, “Recycling of waste tire by pyrolysis to recover carbon black: Alternative & environment-friendly reinforcing filler for natural rubber compounds,” Compos. Part B Eng., vol. 200, no. April, p. 108346, 2020, doi: 10.1016/j.compositesb.2020.108346.

[48] H. Harahap, H. Nasution, R. Manurung, A. Yustira, and A. A. Rashid, “Physical characteristics of biodegradable pots from empty fruit bunches (EFB) and sawdust waste as planting media,” Case Stud. Chem. Environ. Eng., vol. 11, Jun. 2025, doi: 10.1016/j.cscee.2025.101193.

[49] C. Ramos-oliveira, M. Ferreira, I. Belo, and A. Oliva-teles, “Effectiveness of High-Solid Loading Treatments to Enhance Nutrient and Antioxidant Bioavailability in Codium tomentosum,” pp. 1–16, 2025.

[50] Y. Fan, G. D. Fowler, and M. Zhao, The past, present and future of carbon black as a rubber reinforcing filler – A review, vol. 247. Elsevier B.V., 2020. doi: 10.1016/j.jclepro.2019.119115.

[51] N. A. Ramlee, M. Jawaid, E. S. Zainudin, and S. A. K. Yamani, “Tensile, physical and morphological properties of oil palm empty fruit bunch/sugarcane bagasse fibre reinforced phenolic hybrid composites,” J. Mater. Res. Technol., vol. 8, no. 4, pp. 3466–3474, 2019, doi: 10.1016/j.jmrt.2019.06.016.

[52] R. Chollakup, S. Suethao, P. Suwanruji, J. Boonyarit, and W. Smitthipong, “Mechanical properties and dissipation energy of carbon black / rubber composites,” 2021, doi: 10.1177/26349833211005476.

[53] M. F. P. Ferreira, B. F. H. Oliveira, W. B. S. Pinheiro, N. F. Correa, L. F. França, and N. F. P. Ribeiro, “Generation of biofuels by slow pyrolysis of palm empty fruit bunches: Optimization of process variables and characterization of physical-chemical products,” Biomass and Bioenergy, vol. 140, p. 105707, 2020, doi: https://doi.org/10.1016/j.biombioe.2020.105707.

[54] N. Hayeemassae, K. Waysateh, S. Sootaranon, and A. Masa, “Jurnal Teknologi EFFECT OF VULCANIZATION SYSTEMS AND CROSSLINK DENSITY ON TENSILE PROPERTIES AND NETWORK STRUCTURES OF NATURAL,” vol. 6, pp. 181–187, 2022.

[55] V. Dananjaya, Y. Somarathna, S. Siriwardena, N. Sirimuthu, L. Karunanayake, and C. Abeykoon, “Effects of Latex Type and Processed-Mica Waste Loading on the Structural and Thermo-Physical Properties of Natural Rubber Latex Foam Composites,” Int. J. Light. Mater. Manuf., 2023, doi: 10.1016/j.ijlmm.2023.12.002.

Downloads

Download data is not yet available.